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At the end of the 19th century, physics had evolved to the point at which classical mechanics could cope with highly complex problems involving macroscopic situations; thermodynamics and kinetic theory were well established; geometrical and physical optics could be understood in terms of electromagnetic waves; and the conservation laws for energy and momentum (and mass) were widely accepted. So profound were these and other developments that it was generally accepted that all the important laws of physics had been discovered and that, henceforth, research would be concerned with clearing up minor problems and particularly with improvements of method and measurement. However, around 1900 serious doubts arose about the completeness of the classical theories—the triumph of Maxwell's theories, for example, was undermined by inadequacies that had already begun to appear—and their inability to explain certain physical phenomena, such as the energy distribution in blackbody radiation and the photoelectric effect, while some of the theoretical formulations led to paradoxes when pushed to the limit. Prominent physicists such as Hendrik Lorentz, Emil Cohn, Ernst Wiechert and Wilhelm Wien believed that some modification of Maxwell's equations might provide the basis for all physical laws. These shortcomings of classical physics were never to be resolved and new ideas were required. At the beginning of the 20th century a major revolution shook the world of physics, which led to a new era, generally referred to as modern physics.[43] Radiation experiments J. J. Thomson (1856–1940) was a British physicist who discovered electrons and isotopes, and invented the mass spectrometer. Thomson was awarded the 1906 Nobel Prize in Physics. In the 19th century, experimenters began to detect unexpected forms of radiation: Wilhelm Röntgen caused a sensation with his discovery of X-rays in 1895; in 1896 Henri Becquerel discovered that certain kinds of matter emit radiation on their own accord. In 1897, J. J. Thomson discovered the electron, and new radioactive elements found by Marie and Pierre Curie raised questions about the supposedly indestructible atom and the nature of matter. Marie and Pierre coined the term "radioactivity" to describe this property of matter, and isolated the radioactive elements radium and polonium. Ernest Rutherford and Frederick Soddy identified two of Becquerel's forms of radiation with electrons and the element helium. Rutherford identified and named two types of radioactivity and in 1911 interpreted experimental evidence as showing that the atom consists of a dense, positively charged nucleus surrounded by negatively charged electrons. Classical theory, however, predicted that this structure should be unstable. Classical theory had also failed to explain successfully two other experimental results that appeared in the late 19th century. One of these was the demonstration by Albert Michelson and Edward Morley—known as the Michelson–Morley experiment—which showed there did not seem to be a preferred frame of reference, at rest with respect to the hypothetical luminiferous ether, for describing electromagnetic phenomena. Studies of radiation and radioactive decay continued to be a preeminent focus for physical and chemical research through the 1930s, when the discovery of nuclear fission opened the way to the practical exploitation of what came to be called "atomic" energy. Albert Einstein's theory of relativity In 1905 a young, 26-year-old German physicist (then a Bern patent clerk) named Albert Einstein (1879–1955), showed how measurements of time and space are affected by motion between an observer and what is being observed. To say that Einstein's radical theory of relativity revolutionized science is no exaggeration. Although Einstein made many other important contributions to science, the theory of relativity alone represents one of the greatest intellectual achievements of all time. Although the concept of relativity was not introduced by Einstein, his major contribution was the recognition that the speed of light in a vacuum is constant and an absolute physical boundary for motion. This does not have a major impact on a person's day-to-day life since we travel at speeds much slower than light speed. For objects travelling near light speed, however, the theory of relativity states that objects will move slower and shorten in length from the point of view of an observer on Earth. Einstein also derived the famous equation, E = mc2, which reveals the equivalence of mass and energy. Special relativity Albert Einstein (1879–1955), who proposed that gravitation was a result of the presence of mass causing a curvature of space-time, which dictates a path that all freely-moving objects must follow. Further information: History of special relativity Einstein argued that the speed of light was a constant in all inertial reference frames and that electromagnetic laws should remain valid independent of reference frame—assertions which rendered the ether "superfluous" to physical theory, and that held that observations of time and length varied relative to how the observer was moving with respect to the object being measured (what came to be called the "special theory of relativity"). It also followed that mass and energy were interchangeable quantities according to the equation E=mc2. In another paper published the same year, Einstein asserted that electromagnetic radiation was transmitted in discrete quantities ("quanta"), according to a constant that the theoretical physicist Max Planck had posited in 1900 to arrive at an accurate theory for the distribution of blackbody radiation—an assumption that explained the strange properties of the photoelectric effect. The special theory of relativity is a formulation of the relationship between physical observations and the concepts of space and time. The theory arose out of contradictions between electromagnetism and Newtonian mechanics and had great impact on both those areas. The original historical issue was whether it was meaningful to discuss the electromagnetic wave-carrying "ether" and motion relative to it and also whether one could detect such motion, as was unsuccessfully attempted in the Michelson–Morley experiment. Einstein demolished these questions and the ether concept in his special theory of relativity. However, his basic formulation does not involve detailed electromagnetic theory. It arises out of the question: "What is time?" Newton, in the Principia (1686), had given an unambiguous answer: "Absolute, true, and mathematical time, of itself, and from its own nature, flows equably without relation to anything external, and by another name is called duration." This definition is basic to all classical physics. Einstein had the genius to question it, and found that it was incorrect. Instead, each "observer" necessarily makes use of his own scale of time. Furthermore, for two observers in relative motion, their time-scales will differ. This induces a related effect on distance. Both space and time become relative concepts, fundamentally dependent on the observer. Each observer generates his own space-time framework or coordinate system. All observers have equal validity, there being no absolute frame of reference. Motion is relative, but only relative to other observers. What is absolute is stated in Einstein's first relativity postulate: "The basic laws of physics are identical for two observers who have a constant relative velocity with respect to each other." The special relativity made a profound effect on physics: started as a rethinking of the theory of electromagnetism, it found a new symmetry law of nature, now called Poincaré symmetry, that replaced the old Galilean (see above) symmetry. Another long-lasting effect the special relativity exerted on dynamics. Although at the time it was credited as "unification of mass and energy", now it is evident that relativistic dynamics established indeed a firm distinction between the rest mass that is an intrinsic property of a particle, and energy together with momentum that are conserving quantities. The term mass in particle physics underwent a semantic change ans since late 20th century denotes the rest (or invariant) mass almost exclusively, that has little to do with masses of complex physical bodies. See mass in special relativity for the full story. General relativity Further information: History of general relativity In 1916 Einstein was able to generalise this further, to deal with all states of motion including non-uniform acceleration, which became the general theory of relativity. In this theory Einstein also specified a new concept, the curvature of space-time, which described the gravitational effect at every point in space. In fact, the curvature of space-time completely replaced Newton's universal law of gravitation. According to Einstein there was no such thing as a gravitational force. Rather, the presence of a mass causes a curvature of space-time in the vicinity of the mass, and this curvature dictates the space-time path that all freely-moving objects must follow. It was also predicted from this theory that light should be subject to gravity - all of which was verified experimentally. This aspect of relativity explained the phenomena of light bending around the sun, predicted black holes as well as the Cosmic microwave background radiation—a discovery rendering fundamental anomalies in the classic Steady-State hypothesis. For his work on relativity, the photoelectric effect and blackbody radiation, Einstein received the Nobel Prize in 1921. The gradual acceptance of Einstein's theories of relativity and the quantized nature of light transmission, and of Niels Bohr's model of the atom created as many problems as they solved, leading to a full-scale effort to reestablish physics on new fundamental principles. Expanding relativity to cases of accelerating reference frames (the "general theory of relativity") in the 1910s, Einstein posited an equivalence between the inertial force of acceleration and the force of gravity, leading to the conclusion that space is curved and finite in size, and the prediction of such phenomena as gravitational lensing and the distortion of time in gravitational fields. Quantum mechanics Max Planck (1858–1947) Further information: History of quantum mechanics Although relativity resolved the electromagnetic phenomena conflict demonstrated by Michelson and Morley, a second theoretical problem was the explanation of the distribution of electromagnetic radiation emitted by a black body; experiment showed that at shorter wavelengths, toward the ultraviolet end of the spectrum, the energy approached zero, but classical theory predicted it should become infinite. This glaring discrepancy, known as the ultraviolet catastrophe, was solved by the new theory of quantum mechanics. Quantum mechanics is the theory of atoms and subatomic systems. Approximately the first 30 years of the 20th century represent the time of the conception and evolution of the theory. The basic ideas of quantum theory were introduced in 1900 by Max Planck (1858–1947), who was awarded the Nobel Prize for Physics in 1918 for his discovery of the quantified nature of energy. The quantum theory (which previously relied in the "correspondence" at large scales between the quantized world of the atom and the continuities of the "classical" world) was accepted when the Compton Effect established that light carries momentum and can scatter off particles, and when Louis de Broglie asserted that matter can be seen as behaving as a wave in much the same way as electromagnetic waves behave like particles (wave–particle duality). Werner Heisenberg (1901–1976) In 1905, Einstein used the quantum theory to explain the photoelectric effect, and in 1913 the Danish physicist Niels Bohr used the same constant to explain the stability of Rutherford's atom as well as the frequencies of light emitted by hydrogen gas. The quantized theory of the atom gave way to a full-scale quantum mechanics in the 1920s. New principles of a "quantum" rather than a "classical" mechanics, formulated in matrix-form by Werner Heisenberg, Max Born, and Pascual Jordan in 1925, were based on the probabilistic relationship between discrete "states" and denied the possibility of causality. Quantum mechanics was extensively developed by Heisenberg, Wolfgang Pauli, Paul Dirac, and Erwin Schrödinger, who established an equivalent theory based on waves in 1926; but Heisenberg's 1927 "uncertainty principle" (indicating the impossibility of precisely and simultaneously measuring position and momentum) and the "Copenhagen interpretation" of quantum mechanics (named after Bohr's home city) continued to deny the possibility of fundamental causality, though opponents such as Einstein would metaphorically assert that "God does not play dice with the universe".[44] The new quantum mechanics became an indispensable tool in the investigation and explanation of phenomena at the atomic level. Also in the 1920s, Satyendra Nath Bose's work on photons and quantum mechanics provided the foundation for Bose–Einstein statistics, the theory of the Bose–Einstein condensate. The spin–statistics theorem established that, in quantum mechanics, any particle may be either a boson (that means its statistics is Bose–Einstein) or a fermion (that means its statistics is Fermi–Dirac). It was later found that all fundamental bosons transmit forces, like the photon that transmits light. Fermions are particles "like electrons and nucleons" and generally comprise the matter. Fermi–Dirac statistics later found numerous applications from astrophysics (see degenerate matter) to semiconductors. |
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